Using ICP-OES and SEM-EDX in biosorption studies
نویسندگان
چکیده
We have compared the analytical results obtained by inductively coupled plasma optical emission spectroscopy (ICP-OES) and by scanning electron microscopy with an energy dispersive X-ray analytical system (SEM-EDX) in order to explore the mechanism of metal ions biosorption by biomass using two independent methods. The marine macroalga Enteromorpha sp. was enriched with Cu(II), Mn(II), Zn(II), and Co(II) ions via biosorption, and the biosorption capacity of alga determined from the solution and biomass composition before and after biosorption process was compared. The first technique was used to analyze the composition of the natural and metal-loaded biomass, and additionally the composition of the solution before and after biosorption. The second technique was used to obtain a picture of the surface of natural and metal ion-loaded macroalgae, to map the elements on the cell wall of dry biomass, and to determine their concentration before and after biosorption. ICP-OES showed a better precision and lower detection limit than EDX, but SEM-EDX gave more information regarding the sample composition of Enteromorpha sp. Both techniques confirmed that biosorption is a surface phenomenon, in which alkali and alkaline earth metal ions were exchanged by metal ions from aqueous solution.FigureThe advantages and disadvantages of ICP-OES and SEM-EDX techniques ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1007/s00604-010-0468-0) contains supplementary material, which is available to authorized users.
منابع مشابه
Biosorption of Microelements by Spirulina: Towards Technology of Mineral Feed Supplements
Surface characterization and metal ion adsorption properties of Spirulina sp. and Spirulina maxima were verified by various instrumental techniques. FTIR spectroscopy and potentiometric titration were used for qualitative and quantitative determination of metal ion-binding groups. Comparative FTIR spectra of natural and Cu(II)-treated biomass proved involvement of both phosphoryl and sulfone gr...
متن کاملCharacterisation of airborne particulates and associated trace metals deposited on tree bark by ICP-OES, ICP-MS, SEM-EDX and laser ablation ICP-MS
Particulate matter accumulated on tree bark specimens was examined in order to investigate its potential use as a natural monitor to study the impact on local atmospheric conditions. Tree bark from sargent cherry (Prunus sargentii) and sugar maple (Acer saccharum Marsh) trees was collected from four locations: Drax (North Yorkshire), Darley Dale (Derbyshire), Galway (Ireland) and Tristan da Cun...
متن کاملUsing SEM-EDX and ICP-OES to Investigate the Elemental Composition of Green Macroalga Vaucheria sessilis
The biomass of Vaucheria sessilis forms algal mats in many freshwaters. There is a need to find the method of algal biomass utilization. Vaucheria sessilis is a rich source of micro- and macronutrients and can be used as a soil amendment. In the paper, the elemental composition of enriched, via bioaccumulation process, macroalga was investigated. For this purpose, two independent techniques wer...
متن کاملA Qualitative and Quantitative Analysis of Arsenic Sulphide in Potassium Chlorate Based Crude Bomb Residue Samples of Case Studies Using Edxrf, Sem Edx and Icp Aes Instrumental
متن کامل
Determination of titanium and vanadium in Ziegler-Natta catalysts by inductively coupled plasma atomic emission spectrometry.
A method for the determination of Ti and V using inductively coupled plasma atomic emission spectrometry (ICP OES) in Ziegler-Natta polymerization catalysts is proposed. The concentrations of both Ti and V are efficiently determined after catalyst acid digestion with a mixture of HNO3 + HCl + HF and heating (160 degrees C for 6 h) or with 10% (v/v) H2SO4 and heating (160 degrees C for 6 h) or w...
متن کامل